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Question

Cu2+ + 2e ¾® Cu; log[Cu2+] vs Ered graph is of the type shown in figure where OA = 0.34V, then electrode potential of the half cell of Cu/Cu2+ (0.1 M) will be

  1. – 0.34 + fraction numerator 0.059 over denominator 2 end fractionV    
  2. 0.34 + 0.059V    
  3. 0.34 V    
  4. None    

The correct answer is: – 0.34 + fraction numerator 0.059 over denominator 2 end fractionV


    E subscript c u divided by C u to the power of 2 plus end exponent end subscript equals E subscript C u divided by C u to the power of 2 plus end exponent end subscript superscript 0 end superscript minus fraction numerator 0.059 over denominator 2 end fraction log invisible function application left square bracket C u to the power of 2 plus end exponent right square bracket
    if log[Cu2+] = 0, i.e. [Cu2+] = 1 M then E subscript C u divided by C u to the power of 2 plus end exponent end subscript equals E subscript C u divided by C u to the power of 2 plus end exponent end subscript superscript 0 end superscript
    or OA = E subscript C u divided by C u to the power of 2 plus end exponent end subscript superscript 0 end superscript equals negative E subscript C u to the power of 2 plus end exponent divided by C u end subscript superscript 0 end superscript = – 0.34V
    Now E subscript C u divided by C u to the power of 2 plus end exponent end subscript = – 0.34 – fraction numerator 0.059 over denominator 2 end fraction log invisible function application 0.1 = – 0.34 + fraction numerator 0.059 over denominator 2 end fractionV

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