Chemistry-
General
Easy

Question

The reactivity of acid derivatives in general follows the order :

The above order of reactivity can be explained in terms of the : (i) Basicity of leaving group (ii) Resonance effect (iii) Inductive effect Weaker is the basic character of leaving group, more is the reactivity of acid derivative. In general, all the acid derivatives show resonance as follows:

More is the stabilization, lesser is the reactivity and vice-versa.
Which of the most reactive acid derivative?

  1. R minus C O C l    
  2. left parenthesis R C O right parenthesis subscript 2 end subscript O    
  3. RCOOR    
  4. R C O N H subscript 2 end subscript    

The correct answer is: R minus C O C l

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General
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The reactivity of acid derivatives in general follows the order :

The above order of reactivity can be explained in terms of the : (i) Basicity of leaving group (ii) Resonance effect (iii) Inductive effect Weaker is the basic character of leaving group, more is the reactivity of acid derivative. In general, all the acid derivatives show resonance as follows:

More is the stabilization, lesser is the reactivity and vice-versa.
Which among the following anions is the most basic ?

The reactivity of acid derivatives in general follows the order :

The above order of reactivity can be explained in terms of the : (i) Basicity of leaving group (ii) Resonance effect (iii) Inductive effect Weaker is the basic character of leaving group, more is the reactivity of acid derivative. In general, all the acid derivatives show resonance as follows:

More is the stabilization, lesser is the reactivity and vice-versa.
Which among the following anions is the most basic ?

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Observe the esterification mechanisms for primary and tertiary alcohols.
Type.1

Mechanism

Type. 2

Mechanism


Observe the esterification mechanisms for primary and tertiary alcohols.
Type.1

Mechanism

Type. 2

Mechanism


chemistry-General
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Observe the esterification mechanisms for primary and tertiary alcohols.
Type.1

Mechanism

Type. 2

Mechanism

C H subscript 3 end subscript minus C O O H plus C subscript 2 end subscript H subscript 5 end subscript stack O with 18 on top H stack ⟶ with text  Conc.  end text H subscript 2 end subscript S O subscript 4 end subscript on top left parenthesis P right parenthesis
C H subscript 3 end subscript minus C O O H plus open parentheses C H subscript 3 end subscript close parentheses subscript 3 end subscript C minus stack O with 18 on top H stack ⟶ with text  Conc.  end text H subscript 2 end subscript S O subscript 4 end subscript on top open parentheses Q close parentheses
In the above reaction (P) and (Q) are respectively :

Observe the esterification mechanisms for primary and tertiary alcohols.
Type.1

Mechanism

Type. 2

Mechanism

C H subscript 3 end subscript minus C O O H plus C subscript 2 end subscript H subscript 5 end subscript stack O with 18 on top H stack ⟶ with text  Conc.  end text H subscript 2 end subscript S O subscript 4 end subscript on top left parenthesis P right parenthesis
C H subscript 3 end subscript minus C O O H plus open parentheses C H subscript 3 end subscript close parentheses subscript 3 end subscript C minus stack O with 18 on top H stack ⟶ with text  Conc.  end text H subscript 2 end subscript S O subscript 4 end subscript on top open parentheses Q close parentheses
In the above reaction (P) and (Q) are respectively :

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In the Hofmann rearrangement an unsubstituted amide is treated with sodium hydroxide and bromine to give a primary amine that has one carbon lesser than starting amide.
General reaction :

Mechanism :

If the migrating group is chiral then its configuration is retained. Electron releasing effects in the migrating group increases reactivity of Hofmann rearrangement.

In the Hofmann rearrangement an unsubstituted amide is treated with sodium hydroxide and bromine to give a primary amine that has one carbon lesser than starting amide.
General reaction :

Mechanism :

If the migrating group is chiral then its configuration is retained. Electron releasing effects in the migrating group increases reactivity of Hofmann rearrangement.

chemistry-General
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In the Hofmann rearrangement an unsubstituted amide is treated with sodium hydroxide and bromine to give a primary amine that has one carbon lesser than starting amide.
General reaction :

Mechanism :

If the migrating group is chiral then its configuration is retained. Electron releasing effects in the migrating group increases reactivity of Hofmann rearrangement.
Arrange the following amides according to their relative reactivity when reacted with Br2 in excess of strong base
I) 
II) 
III) 
IV) 

In the Hofmann rearrangement an unsubstituted amide is treated with sodium hydroxide and bromine to give a primary amine that has one carbon lesser than starting amide.
General reaction :

Mechanism :

If the migrating group is chiral then its configuration is retained. Electron releasing effects in the migrating group increases reactivity of Hofmann rearrangement.
Arrange the following amides according to their relative reactivity when reacted with Br2 in excess of strong base
I) 
II) 
III) 
IV) 

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A bent arc shaped sealed glass tube filled with water is accelerated horizontally with acceleration a. A small air bubble inside it is found to be stuck at 1 cm from vertical axis. Neglect surface tension. What is the acceleration of the tube.

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A pan balance has a container of water with an overflow spout on the right-hand pan as shown. It is full of water right up to the overflow spout. A container on the left-hand pan is positioned to catch any water that overflows. The entire apparatus is adjusted so that it’s balanced. A brass weight on the end of a string is then lowered into the water, but not allowed to rest on the bottom of the container. What happens next?

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