Chemistry-
General
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Question

The van der Waals constant for gasesblank A comma blank B comma and C are as follows:

Which gas has the highest critical temperature?

  1. A    
  2. B    
  3. C    
  4. None    

The correct answer is: B


    Since, T subscript c end subscript equals fraction numerator 8 a over denominator 27 R b end fraction
    Hint: Gas B has the highest value of a, therefore, it has the highest critical temperature

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    v is molecular velocity
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    Let us define increment N subscript v end subscript, which is equal to the number of molecules between the velocity range v and v plus increment v, given by
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    a equals square root of fraction numerator M subscript 0 end subscript over denominator 2 pi R T end fraction end root and b equals square root of fraction numerator M subscript 0 end subscript over denominator 2 R T end fraction end root
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    Where
    v is molecular velocity
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    Let us define increment N subscript v end subscript, which is equal to the number of molecules between the velocity range v and v plus increment v, given by
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    The figure given below shows three glass chambers that are connected by valves of negligible volume. At the outset of an experiment, the valves are closed and the chambers contain the gases as detailed in the diagram. All the chambers are at the temperature of 300 K and external pressure of 1.0 atm
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